Rh2(OAc)4-AgOTf Cooperative Catalysis in Cyclization/Three-Component Reactions for Concise Synthesis of 1,2-Dihydroisoquinolines

Hu, Wenhao

Rh₂(OAc)₄-AgOTf Cooperative Catalysis in Cyclization/Three-Component Reactions for Concise Synthesis of 1,2-Dihydroisoquinolines

Posted on 2010-02-19 - 00:00

Dirhodium acetate and silver triflate cooperatively catalyzed tandem cyclization/three-component reactions of 2-alkynylarylaldimines with diazo compounds and water or alcohols are reported to afford 1,2-dihydroisoquinolines bearing α-hydroxyl-β-amino carboxylate skeleton in high yield.

CITE THIS COLLECTION

Guo, Zhenqiu; Cai, Mei; Jiang, Jun; Yang, Liping; Hu, Wenhao (2016). Rh₂(OAc)₄-AgOTf Cooperative Catalysis in Cyclization/Three-Component Reactions for Concise Synthesis of 1,2-Dihydroisoquinolines. ACS Publications. Collection. https://doi.org/10.1021/ol902409u

https://doi.org/10.1021/ol902409u

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