Regioselective One-Pot Benzoylation of Triol and Tetraol
Arrays in Carbohydrates
Posted on 2018-06-22 - 18:49
Protection of 2,3,4-O-unprotected α-galacto-
and α-fucopyranosides with BzCN and DMAP/DIPEA as the base afforded
directly and regioselectively the 3-O-unprotected
derivatives. The rationale for these studies was to take advantage
of the eventual cooperativity of the “cyanide effect”
and “the alkoxy group mediated diol effect”. This way,
even the totally unprotected α-galactopyranosides could be regioselectively
transformed into the corresponding 2,4,6-O-protected
derivatives. The great utility of these building blocks was demonstrated
in efficient trisaccharide syntheses.
CITE THIS COLLECTION
DataCite
3 Biotech
3D Printing in Medicine
3D Research
3D-Printed Materials and Systems
4OR
AAPG Bulletin
AAPS Open
AAPS PharmSciTech
Abhandlungen aus dem Mathematischen Seminar der Universität Hamburg
ABI Technik (German)
Academic Medicine
Academic Pediatrics
Academic Psychiatry
Academic Questions
Academy of Management Discoveries
Academy of Management Journal
Academy of Management Learning and Education
Academy of Management Perspectives
Academy of Management Proceedings
Academy of Management Review
Li, Tong; Li, Tianlu; Cui, Tongxiao; Sun, Yajing; Wang, Fengshan; Cao, Hongzhi; et al. (2018). Regioselective One-Pot Benzoylation of Triol and Tetraol
Arrays in Carbohydrates. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b01446
or
Select your citation style and then place your mouse over the citation text to select it.
SHARE
Usage metrics
Read the peer-reviewed publication
AUTHORS (8)
TL
Tong Li
TL
Tianlu Li
TC
Tongxiao Cui
YS
Yajing Sun
FW
Fengshan Wang
HC
Hongzhi Cao
RS
Richard R. Schmidt
PP
Peng Peng