Reaction of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with
Me3SiC⋮CR. Synthesis and Structural Characterization of
Mononuclear Ruthenium Bis(vinylidene) and Vinylvinylidene
Complexes
Posted on 2006-05-22 - 00:00
The substituent R plays a crucial role in the reaction
of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with Me3SiC⋮CR. If R = Me3Si, this reaction led to the isolation of the first
mononuclear bis(vinylidene)metal complex. If R = H, a vinylvinylidenemetal complex was generated.
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Sun, Yi; Chan, Hoi-Shan; Dixneuf, Pierre H.; Xie, Zuowei (2016). Reaction of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with
Me3SiC⋮CR. Synthesis and Structural Characterization of
Mononuclear Ruthenium Bis(vinylidene) and Vinylvinylidene
Complexes. ACS Publications. Collection. https://doi.org/10.1021/om060211y
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