Quaternary Layered Ni-Rich NCMA Cathode for Lithium-Ion
Batteries
Version 2 2019-02-01, 02:43Version 2 2019-02-01, 02:43
Version 1 2019-01-30, 21:29Version 1 2019-01-30, 21:29
Posted on 2019-02-01 - 02:43
Li[Ni1–x–yCoxAly]O2 (NCA) and Li[Ni1–x–yCoxMny]O2 (NCM) cathodes have been the archetypes of current
high-energy-density cathodes for Li-ion batteries. A hybrid of NCA
and NCM cathodes, a quaternary system consisting of Li[Ni0.89Co0.05Mn0.05Al0.01]O2 (NCMA) was benchmarked against NCM and NCA with similar Ni contents.
The quaternary NCMA cathode delivered a capacity of 228 mAh g–1 and outperformed the benchmarking cathodes in long-term
cycling stability (85% after 1000 cycles). The reduction in the volume
change during deintercalation and the enhanced intrinsic mechanical
strength confirmed by the single-particle compression test suppressed
the microcrack nucleation and propagation. Microcrack suppression
was important because microcracks serve as channels for electrolyte
infiltration and lead to subsequent surface degradation of internal
surfaces. The proposed NCMA cathode provides extra cycling stability,
which is essential for electric vehicles, which require a long battery
life and improves the thermal stability of the cathode, which contributes
to a safer battery.
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