Proton Conduction in 2D Aza-Fused Covalent Organic
Frameworks
Version 2 2019-01-11, 18:21
Version 1 2019-01-07, 17:38
Posted on 2019-01-11 - 18:21
This
paper describes the first demonstration of a general concept
for achieving facile proton conduction within a class of layered two-dimensional
aza-fused π-conjugated covalent organic frameworks (COFs). The
built-in phenanthroline moieties promote efficient adsorption of water
and acidification by H3PO4 to produce excellent
proton conductivities of 10–5 and 10–3 S/cm for the pristine and acidified analogues, respectively. These
molecular design concepts are poised for development of highly stable
proton-conducting materials.
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Meng, Zheng; Aykanat, Aylin; Mirica, Katherine A. (2019). Proton Conduction in 2D Aza-Fused Covalent Organic
Frameworks. ACS Publications. Collection. https://doi.org/10.1021/acs.chemmater.8b03897
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AUTHORS (3)
ZM
Zheng Meng
AA
Aylin Aykanat
KM
Katherine A. Mirica