Preparation of Functionalized α,β-Unsaturated
Sulfonamides via Olefin Cross-Metathesis

Grela, Karol

Preparation of Functionalized α,β-Unsaturated Sulfonamides via Olefin Cross-Metathesis

Posted on 2020-06-17 - 15:35

The synthesis of functionalized α,β-unsaturated sulfonamides by means of cross-metathesis of vinyl sulfonamides and olefins has been developed. The reaction proceeds smoothly in the presence of Hoveyda–Grubbs catalyst and its nitro analogue, providing a wide range of substituted products. The usefulness of this methodology has been proven in the preparation of new derivatives of biologically active ingredients, moxifloxacin and naratriptan.

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Woźniak, Łukasz; Rajkiewicz, Adam A.; Monsigny, Louis; Kajetanowicz, Anna; Grela, Karol (2020). Preparation of Functionalized α,β-Unsaturated Sulfonamides via Olefin Cross-Metathesis. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.0c01471

https://doi.org/10.1021/acs.orglett.0c01471

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