Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane
Precursors
Posted on 2020-10-02 - 20:31
Quantum
chemical calculations were used to determine the energetic
viability of several mechanisms for formation of ladderanes from oligocyclopropanes.
Pathways involving radical cations, diradicals, and carbocations were
considered, and a hybrid of carbocation and radical cation pathways
was predicted to have the lowest overall barrier.
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Chen, Shu-Sen; Tantillo, Dean J. (2020). Potential for Ladderane (Bio)synthesis from Oligo-Cyclopropane
Precursors. ACS Publications. Collection. https://doi.org/10.1021/acsomega.0c03735
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AUTHORS (2)
- SCShu-Sen ChenDTDean J. Tantillo
CATEGORIES
- Biophysics
- Biochemistry
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