Polymorphous Indium Metal–Organic Frameworks
Based on a Ferrocene Linker: Redox Activity, Porosity, and Structural
Diversity
Posted on 2020-07-06 - 18:07
The metallocene-based linker molecule
1,1′-ferrocenedicarboxylic acid (H2FcDC) was used
to synthesize four different polymorphs of composition [In(OH)(FeC12H8O4)]. Using conventional solvent-based
synthesis methods and varying the synthetic parameters such as metal
source, reaction temperature, and solvent, two different MOFs and
one 1D-coordination polymer denoted as CAU-43 (1), In-MIL-53-FcDC_a
(2), and In-FcDC (3) were obtained. Furthermore,
thermal treatment of CAU-43 (1) at 190 °C under
vacuum yielded a new polymorph of 2, In-MIL-53-FcDC_b
(4). Both MOFs 2 and 4 crystallize
in a MIL-53 type structure, but in different space groups C2/m for 2 and P1̅ for 4. The structures of the four title compounds
were determined by single-crystal X-ray diffraction (SCXRD), powder
X-ray diffraction (PXRD), or a combination of three-dimensional electron
diffraction measurements (3D ED) and PXRD. N2 sorption
experiments of 1, 2, and 4 showed
specific surface areas of 355 m2 g–1,
110 m2 g–1, and 140 m2 g–1, respectively. Furthermore, the electronic properties
of the title compounds were characterized via Mössbauer and
EPR spectroscopy. All Mössbauer spectra showed the characteristic
doublet, proving the persistence of the ferrocene moiety. In the cases
of 1, 3, and 4, appreciable
impurities of ferrocenium ions could be detected by electron paramagnetic
resonance spectroscopy. Cyclovoltammetric experiments were performed
to demonstrate the accessible redox activity of the linker molecule
of the title compounds. A redox process of FcDC2– with oxidation (between 0.86 and 0.97 V) and reduction wave (between
0.69 and 0.80 V) was observed.
CITE THIS COLLECTION
DataCite
3 Biotech
3D Printing in Medicine
3D Research
3D-Printed Materials and Systems
4OR
AAPG Bulletin
AAPS Open
AAPS PharmSciTech
Abhandlungen aus dem Mathematischen Seminar der Universität Hamburg
ABI Technik (German)
Academic Medicine
Academic Pediatrics
Academic Psychiatry
Academic Questions
Academy of Management Discoveries
Academy of Management Journal
Academy of Management Learning and Education
Academy of Management Perspectives
Academy of Management Proceedings
Academy of Management Review
Benecke, Jannik; Grape, Erik Svensson; Fuß, Alexander; Wöhlbrandt, Stephan; Engesser, Tobias A.; Inge, A. Ken; et al. (2020). Polymorphous Indium Metal–Organic Frameworks
Based on a Ferrocene Linker: Redox Activity, Porosity, and Structural
Diversity. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.0c01124
or
Select your citation style and then place your mouse over the citation text to select it.
SHARE
Usage metrics
Read the peer-reviewed publication
AUTHORS (8)
JB
Jannik Benecke
EG
Erik Svensson Grape
AF
Alexander Fuß
SW
Stephan Wöhlbrandt
TE
Tobias A. Engesser
AI
A. Ken Inge
NS
Norbert Stock
HR
Helge Reinsch