Pd/Cu-Catalyzed Domino Cyclization/Deborylation of
Alkene-Tethered Carbamoyl Chloride and 1,1-Diborylmethane
Posted on 2020-08-05 - 18:35
Reported herein is a palladium/copper
cooperative-catalyzed dicarbofunctionalization of alkene-tethered
carbamoyl chlorides with 1,1-diborylmethane. This cyclization/deborylation
cascade strategy allows for the expedient formation of the versatile
borylated 3,3-disubstituted oxindole skeleton, allowing for further
functionalization via the derivatization of the carbon–boron
bond.
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Zhang, Chenhuan; Wu, Xianqing; Wang, Chenchen; Zhang, Chengxi; Qu, Jingping; Chen, Yifeng (2020). Pd/Cu-Catalyzed Domino Cyclization/Deborylation of
Alkene-Tethered Carbamoyl Chloride and 1,1-Diborylmethane. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.0c02211
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AUTHORS (6)
CZ
Chenhuan Zhang
XW
Xianqing Wu
CW
Chenchen Wang
CZ
Chengxi Zhang
JQ
Jingping Qu
YC
Yifeng Chen