Model Reactions for the Enantioselective Synthesis
of γ‑Rubromycin: Stereospecific Intramolecular Photoredox
Cyclization of an ortho-Quinone Ether to a Spiroacetal
Version 2 2018-06-25, 18:38
Version 1 2018-06-22, 18:48
Posted on 2018-06-25 - 18:38
A model study for the enantioselective
total synthesis of γ-rubromycin
has revealed a promising approach for constructing the chiral, nonracemic
bicyclic spiroacetal via the stereospecific photoredox reaction of
1,2-naphthoquinone ether.
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Wakita, Fumihiro; Ando, Yoshio; Ohmori, Ken; Suzuki, Keisuke (2018). Model Reactions for the Enantioselective Synthesis
of γ‑Rubromycin: Stereospecific Intramolecular Photoredox
Cyclization of an ortho-Quinone Ether to a Spiroacetal. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b01475
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