Metal-Free,
Visible-Light-Enabled Direct C3–H
Arylation of Anthranils

Hashmi, A. Stephen K.

Metal-Free, Visible-Light-Enabled Direct C3–H Arylation of Anthranils

Posted on 2020-07-07 - 18:41

An eosin Y disodium salt-catalyzed photoredox C–H arylation of anthranils is reported. A variety of aryl diazonium tetrafluoroborates were used as aryl sources, providing the C3 cross-coupled products. The in situ generated reactive radicals were trapped by anthranils, providing an alternative method to transition-metal-catalyzed C–H arylations of anthranils. Gold-catalyzed downstream transformations demonstrate the synthetic potential of these valuable building blocks.

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Adak, Tapas; Hu, Chao; Rudolph, Matthias; Li, Jun; Hashmi, A. Stephen K. (2020). Metal-Free, Visible-Light-Enabled Direct C3–H Arylation of Anthranils. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.0c01999

https://doi.org/10.1021/acs.orglett.0c01999

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