Melding Caged Compounds with Supramolecular Containers:
Photogeneration and Miscreant Behavior of the Coumarylmethyl Carbocation
Posted on 2017-06-19 - 23:48
By merging well-established
concepts of supramolecular chemistry,
protecting group strategy, and photochemistry, we have solubilized
in water hydrophobic organic molecules consisting of a photoactive
protecting group and masked carboxylic acids, released the desired
acid, and confined a reactive carbocation intermediate within a capsule.
Confinement of the photogenerated carbocation brought out the latent
radical-like behavior. This observation is consistent with the recent
theoretical prediction of the 7-(diethylamino)coumarinyl-4-methyl
carbocation having a triplet diradical ground-state electronic contribution.
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Kamatham, Nareshbabu; P. Da Silva, José; Givens, Richard S.; Ramamurthy, V. (2017). Melding Caged Compounds with Supramolecular Containers:
Photogeneration and Miscreant Behavior of the Coumarylmethyl Carbocation. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b01572
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AUTHORS (4)
NK
Nareshbabu Kamatham
JP
José P. Da Silva
RG
Richard S. Givens
VR
V. Ramamurthy