Light-Switchable Polymer Adhesive Based on Photoinduced Reversible Solid-to-Liquid Transitions

The development of switchable adhesives for reversible bonding and debonding can overcome the problems associated with conventional adhesives in separating, recycling, and repairing glued surfaces. Here, a photoresponsive azobenzene-containing polymer (azopolymer) is developed for photocontrolled adhesion. The azopolymer P1 (poly­(6-(4-(p-tolyldiazenyl)­phenoxy)­hexyl acrylate)) exhibits photoinduced reversible solid-to-liquid transitions due to trans–cis photoisomerization. Trans P1 is a solid that glues two substrates with a stiffness comparable to that of conventional adhesives. UV light induces trans-to-cis isomerization, liquefies P1, weakens the adhesion, and facilitates the separation of glued substrates. Conversely, visible light induces cis-to-trans isomerization, solidifies P1, and enhances the adhesion. P1 enables photocontrolled reversible adhesion for various substrates with different wettability, chemical compositions, and surface roughness. P1 can also be implemented in both dry and wet environments. Light can control the adhesion process with high spatiotemporal resolution when using P1 as a switchable adhesive. Photoinduced reversible solid-to-liquid transitions represent a strategy for materials recycling and automated production processes that require reversible bonding and debonding.