Isomerically Pure syn-Anthradithiophenes: Synthesis, Properties, and FET Performance
Posted on 2012-07-20 - 00:00
The synthesis of isomerically pure syn-anthradithiophene derivatives (syn-ADTs) is described. X-ray crystallography is used to compare the solid-state arrangement of syn-ADT derivatives 2a,b to the analogous mixture of syn- and anti-ADTs. Single-crystal OFETs based on isomerically pure syn-ADTs 2a,b display device performance comparable to those based on a mixture of ADT isomers syn/anti-2a,b with mobilities as high as 1 cm2/(V s).
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Lehnherr, Dan; Waterloo, Andreas R.; Goetz, Katelyn P.; Payne, Marcia M.; Hampel, Frank; Anthony, John E.; et al. (2016). Isomerically Pure syn-Anthradithiophenes: Synthesis, Properties, and FET Performance. ACS Publications. Collection. https://doi.org/10.1021/ol301503k