American Chemical Society

Investigation of the Electrocatalytic Reduction of Peroxydisulfate Using Scanning Electrochemical Microscopy

Posted on 2024-05-16 - 02:29
The elementary steps of the electrocatalytic reduction of S2O82– using the Ru(NH3)63+/2+ redox couple were investigated using scanning electrochemical microscopy (SECM) and steady-state voltammetry (SSV). SECM investigations were carried out in a 0.1 M KCl solution using a 3.5 μm radius carbon ultramicroelectrode (UME) as the SECM tip and a 25 μm radius platinum UME as the substrate electrode. Approach curves were recorded in the positive feedback mode of SECM by reducing Ru(NH3)63+ at the tip electrode and oxidizing Ru(NH3)62+ at the substrate electrode, as a function of the tip–substrate separation and S2O82– concentration. The one-electron reaction between electrogenerated Ru(NH3)62+ and S2O82– yields the unstable S2O83•–, which rapidly dissociates to produce highly oxidizing SO4•–. Because SO4•– is such a strongly oxidizing species, it can be further reduced at both the tip and the substrate, or it can react with Ru(NH3)62+ to regenerate Ru(NH3)63+. SECM approach curves display a complex dependence on the tip–substrate distance, d, due to redox mediation reactions at both the tip and the substrate. Finite element method (FEM) simulations of both SECM approach curves and SSV confirm a previously proposed mechanism for the mediated reduction of S2O82– using the Ru(NH3)63+/2+ redox couple. Our results provide a lower limit for dissociation rate constant of S2O83•– (∼1 × 106 s–1), as well as the rate constants for electron transfer between SO4•– and Ru(NH3)62+ (∼1 × 109 M–1 s–1) and between S2O82– and Ru(NH3)62+ (∼7 × 105 M–1 s–1).


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