Intramolecular σ-Bond Metathesis Between Carbon–Carbon and Silicon–Silicon Bonds

Murakami, Masahiro

Intramolecular σ-Bond Metathesis Between Carbon–Carbon and Silicon–Silicon Bonds

Posted on 2012-06-15 - 00:00

An intramolecular σ-bond metathesis between carbon–carbon and silicon–silicon bonds took place on treatment of a disilane tethered to a cyclobutanone with a palladium(0) catalyst, furnishing a silaindane skeleton as well as an acylsilane functionality at once.

CITE THIS COLLECTION

Ishida, Naoki; Ikemoto, Wataru; Murakami, Masahiro (2016). Intramolecular σ-Bond Metathesis Between Carbon–Carbon and Silicon–Silicon Bonds. ACS Publications. Collection. https://doi.org/10.1021/ol301280u

https://doi.org/10.1021/ol301280u

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