American Chemical Society
Browse

Impact of Thermal Oxidative Stabilization on the Performance of Lignin-Based Carbon Nanofiber Mats

Posted on 2019-03-15 - 08:13
Lignin is a renewable biopolymer considered as a potential precursor for low-cost carbon materials. Thermal oxidative stabilization (TOS) is an important processing step to maintain fiber geometry during carbonization, yet the impact of  TOS on the properties of lignin-based carbon materials has not been clearly identified in the literature. Yield, change in fiber diameter/distribution, elemental composition, and mechanical properties were explored for both stabilized and carbonized lignin fibers. Vibrational spectroscopy and solid-state 13C nuclear magnetic resonance spectroscopy were used to analyze the changes in lignin molecular structure after exposure to various heating conditions during the TOS steps. Further, studies were focused on the effects of TOS conditions on the resulting carbon structure of fiber mats through Raman spectroscopy measurements and electrical conductivity analysis. Although TOS conditions influenced the properties of the oxidized lignin fiber mats, properties of the carbonized samples were invariant to the TOS procedures used in this study over most of the conditions. As a result, there was flexibility for the parameters (time and temperature) in the TOS process when conditioning softwood lignin materials for carbon fibers.

CITE THIS COLLECTION

DataCite
3 Biotech
3D Printing in Medicine
3D Research
3D-Printed Materials and Systems
4OR
AAPG Bulletin
AAPS Open
AAPS PharmSciTech
Abhandlungen aus dem Mathematischen Seminar der Universität Hamburg
ABI Technik (German)
Academic Medicine
Academic Pediatrics
Academic Psychiatry
Academic Questions
Academy of Management Discoveries
Academy of Management Journal
Academy of Management Learning and Education
Academy of Management Perspectives
Academy of Management Proceedings
Academy of Management Review
or
Select your citation style and then place your mouse over the citation text to select it.

SHARE

email
need help?