Hydride Transfer Involved Redox-Neutral Cascade Cyclizations
for Construction of Spirocyclic Bisoxindoles Featuring a [3,4]-Fused
Oxindole Moiety
Version 2 2019-02-12, 16:25
Version 1 2019-02-05, 20:21
Posted on 2019-02-12 - 16:25
The hydride transfer involved redox-neutral
cascade cyclization
has been developed to construct the spirocyclic bisoxindoles featuring
a [3,4]-fused oxindole moiety from rationally designed C4-amine-substituted
isatins, affording the diverse tricyclic [3,4]-fused oxindoles with
three consecutive chiral centers in good yields and excellent diastereoselectivities
(>20:1).
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Li, Shuai-Shuai; Zhu, Shuai; Chen, Chunqi; Duan, Kang; Liu, Qing; Xiao, Jian (2019). Hydride Transfer Involved Redox-Neutral Cascade Cyclizations
for Construction of Spirocyclic Bisoxindoles Featuring a [3,4]-Fused
Oxindole Moiety. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b04100
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