High-Temperature
Spin Crossover in a Mononuclear Six-Coordinate
Cobalt(II) Complex

Julve, Miguel

High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex

Posted on 2014-10-06 - 00:00

The six-coordinate cobalt(II) complex of formula [Co(tppz)₂](tcm)₂ exhibits a thermally induced spin-crossover behavior from a high spin (S = ³/₂) at higher temperatures to a low spin (S = ¹/₂) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.

CITE THIS COLLECTION

Palion-Gazda, Joanna; Świtlicka-Olszewska, Anna; Machura, Barbara; Grancha, Thais; Pardo, Emilio; Lloret, Francesc; et al. (2016). High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex. ACS Publications. Collection. https://doi.org/10.1021/ic501195y

https://doi.org/10.1021/ic501195y

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