First-Principles
Study on Chromium-Substituted α‑Cobalt
Oxyhydroxides for Efficient Oxygen Evolution Reaction
Posted on 2020-06-17 - 14:44
Owing
to their catalytic, electronic, and optical properties, metal
hydroxides are extensively used in energy applications. Despite recent
progress, the synthesis of monolayer metal hydroxides with unique
structures remains a challenge, and their potential use in the oxygen
evolution reaction (OER) has not been fully investigated. Herein,
the fabrication of chromium-substituted α-cobalt hydroxide through
a simple co-precipitation method under optimum conditions at higher
pH is described. Such nanostructures can competently catalyze oxygen
evolution reactions to produce a current density of 10 mA cm–2 at an overpotential of 240 mV in alkaline medium. Microscopic, electrochemical,
and spectroscopic analyses reveal that the exceptional OER performance
originates from thin monolayer sheets with exposed active sites and
partially due to the substitution of α-CoOOH with Cr. The phase
purity is highlighted through powder X-ray diffraction (PXRD), energy-dispersive
X-ray (EDX) mapping, and X-ray photoelectron spectroscopy (XPS) analysis.
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Shamraiz, Umair; Badshah, Amin; Raza, Bareera; Green, Ivan R. (2020). First-Principles
Study on Chromium-Substituted α‑Cobalt
Oxyhydroxides for Efficient Oxygen Evolution Reaction. ACS Publications. Collection. https://doi.org/10.1021/acsaem.0c00719