Fast Photochromism
of the Imidazole Dimers Bridged
by Group 14 Atoms
Posted on 2020-07-07 - 18:39
We developed fast
photochromic imidazole dimers bridged by group
14 atoms. These compounds reversibly break the C–N bond to
generate the colored open-ring biradical form. The colored form thermally
reproduces the initial colorless form in the microsecond time scales.
Furthermore, the color of the biradical can be easily controlled by
the introduction of two different types of the imidazolyl radicals.
These results give attractive insights for the further development
of fast photochromic imidazole dimers.
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Ito, Hiroki; Tanaka, Sho; Mutoh, Katsuya; Abe, Jiro (2020). Fast Photochromism
of the Imidazole Dimers Bridged
by Group 14 Atoms. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.0c02072
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AUTHORS (4)
HI
Hiroki Ito
ST
Sho Tanaka
KM
Katsuya Mutoh
JA
Jiro Abe