Enantioselective Formal
Aza-Diels–Alder Reactions
of Enones with Cyclic Imines Catalyzed by Primary Aminothioureas

Jacobsen, Eric N.

Enantioselective Formal Aza-Diels–Alder Reactions of Enones with Cyclic Imines Catalyzed by Primary Aminothioureas

Posted on 2013-02-06 - 00:00

A highly enantio- and diastereoselective synthesis of indolo- and benzoquinolizidine compounds has been developed through the formal aza-Diels–Alder reaction of enones with cyclic imines. This transformation is catalyzed by a new bifunctional primary aminothiourea that achieves simultaneous activation of both the enone and imine reaction components.

CITE THIS COLLECTION

Lalonde, Mathieu P.; McGowan, Meredeth A.; Rajapaksa, Naomi S.; Jacobsen, Eric N. (2016). Enantioselective Formal Aza-Diels–Alder Reactions of Enones with Cyclic Imines Catalyzed by Primary Aminothioureas. ACS Publications. Collection. https://doi.org/10.1021/ja310718f

https://doi.org/10.1021/ja310718f

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