Electrical Tunable PVDF/Graphene Membrane for Controlled
Molecule Separation
Posted on 2020-06-17 - 10:43
Though
membrane separation has been an efficient and energy-saving
technique for dealing with wasted mixed chemical matter, the concomitant
environmental pollution has become a big issue in the development
of the membrane field. Consequently, use of an active-responsive smart
membrane appears to be a new trend for membrane development in the
coming future, which shows great potential to deal with the obstacles.
Here, we demonstrate the preparation of a smart electric-responsive
membrane, PVDF/graphene composite membrane, in which the graphene
induces self-assembly of PVDF chains, showing a highly β phase
and thus a unique piezoelectric property. The resultant nanochannels
in the membrane could be reversibly adjusted by electric driving,
resulting in tailored alcohol selectivity on the single membrane.
The membrane was utilized to challenge the dehydration of a MeOH/water
mixture, which offered a >99.5 rejection to MeOH molecules with
high
water flux, achieving a precise molecule separation performance. Overall,
the novel active membrane separation process proposed in this work
opens the gates toward the development of a novel generation of an
active smart membrane, which is imperative for the future of a sustainable
society.
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