Double Helices of a Pyridine-Appended Zinc Chlorophyll
Derivative

Otsuki, Joe

Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative

Posted on 2013-04-10 - 00:00

Self-assembled structures formed from a pyridine-appended zinc chlorophyll derivative are reported. While the zinc complex forms cyclic oligomers in chloroform solution, as indicated by ¹H NMR studies (including diffusion-ordered spectroscopy), vapor pressure osmometry, and cold-spray ionization mass spectrometry, it forms double-stranded helical coordination polymers in the solid state, as revealed by single-crystal X-ray analysis.

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Shinozaki, Yoshinao; Richards, Gary; Ogawa, Keizo; Yamano, Akihito; Ohara, Kazuaki; Yamaguchi, Kentaro; et al. (2016). Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative. ACS Publications. Collection. https://doi.org/10.1021/ja400493e

https://doi.org/10.1021/ja400493e

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Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative

AUTHORS (11)

YS
Yoshinao Shinozaki
GR
Gary Richards
KO
Keizo Ogawa
AY
Akihito Yamano
KO
Kazuaki Ohara
KY
Kentaro Yamaguchi
SK
Shin-ichiro Kawano
KT
Kentaro Tanaka
YA
Yasuyuki Araki
TW
Takehiko Wada
JO
Joe Otsuki

KEYWORDS

polymer forms cyclic oligomers osmometry helical chlorophyll analysis coordination spectroscopy ionization chloroform solution 1 H NMR studies Chlorophyll spectrometry Double Helices vapor

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Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative

CITE THIS COLLECTION

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AUTHORS (11)

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KEYWORDS