Diastereoselective Synthesis of Polysubstituted Spirocyclopenta[c]furans by Gold-Catalyzed Cascade Reaction

Xu, Zhenghu

Diastereoselective Synthesis of Polysubstituted Spirocyclopenta[c]furans by Gold-Catalyzed Cascade Reaction

Posted on 2019-01-11 - 20:15

With the synergistic activation of alkynyl alcohols and alkynyl enones by a single gold catalyst, diverse multisubstituted spirocyclopenta[c]furans were synthesized in good to excellent yields under mild conditions. Three rings were constructed efficiently in one pot from easily available acyclic starting materials.

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Qi, Jialin; Teng, Qi; Thirupathi, Nuligonda; Tung, Chen-Ho; Xu, Zhenghu (2019). Diastereoselective Synthesis of Polysubstituted Spirocyclopenta[c]furans by Gold-Catalyzed Cascade Reaction. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.8b03880

https://doi.org/10.1021/acs.orglett.8b03880

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