Cycloadditions of Aromatic Azomethine
Imines with 1,1-Cyclopropane Diesters

Charette, André B.

Cycloadditions of Aromatic Azomethine Imines with 1,1-Cyclopropane Diesters

Posted on 2008-03-06 - 00:00

The cycloaddition of aromatic azomethine imines to 1,1-cyclopropane diesters was achieved using Ni(ClO₄)₂ as catalyst. The methodology gives access to unique tricyclic dihydroquinoline derivatives with dr up to 6.6:1. A nonconcerted mechanism is proposed on the basis of stereochemical analysis of the reaction.

CITE THIS COLLECTION

Perreault, Christian; Goudreau, Sébastien R.; Zimmer, Lucie E.; Charette, André B. (2016). Cycloadditions of Aromatic Azomethine Imines with 1,1-Cyclopropane Diesters. ACS Publications. Collection. https://doi.org/10.1021/ol702414e

https://doi.org/10.1021/ol702414e

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