Cu(II)-Catalyzed 6π-Photocyclization of Non-6π
Substrates

Guo, Hao

Cu(II)-Catalyzed 6π-Photocyclization of Non-6π Substrates

Posted on 2020-06-25 - 19:11

This research successfully achieved a Cu(II)-catalyzed 6π-photocyclization of non-6π substrates. The photoenolization converts ortho-alkylphenyl alkynl ketones into a triene-type intermediate which undergoes the subsequent 6π-photocyclization to give naphthol as the final product. Cu(II) catalyst facilitates both photoenolization and 6π-photocyclization. This research highlighted the tandem reaction strategy and the importance of metal catalysis in photochemistry.

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Zhang, Yanbin; Jin, Ruiwen; Kang, Wenjie; Guo, Hao (2020). Cu(II)-Catalyzed 6π-Photocyclization of Non-6π Substrates. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.0c01854

https://doi.org/10.1021/acs.orglett.0c01854

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