Construction
of Homoallylic Alcohols from Terminal
Alkynes and Aldehydes with Installation of syn-Stereochemistry
Posted on 2014-04-30 - 00:00
A cationic rhodium(I)
catalyst turns 2-silyl-1-alkenylboronate,
readily prepared from a terminal alkyne, into the corresponding allylboronate
species, which immediately undergoes nucleophilic addition to an aldehyde
to give a syn-homoallylic alcohol stereoselectively.
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Miura, Tomoya; Nishida, Yui; Murakami, Masahiro (2016). Construction
of Homoallylic Alcohols from Terminal
Alkynes and Aldehydes with Installation of syn-Stereochemistry. ACS Publications. Collection. https://doi.org/10.1021/ja502169d
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AUTHORS (3)
- TMTomoya MiuraYNYui NishidaMMMasahiro Murakami
