Constructing an AIE Diphenylquinoxaline-Based Luminescent
Europium-Organic Framework for Multiple Substance Sensing
Posted on 2023-05-26 - 13:05
Luminescent
lanthanide metal–organic frameworks (Ln-MOFs)
draw great interest due to their promising luminescent properties
and wide applications in sensor design. In this work, a europium-organic
framework (DPQ-Eu) has been synthesized under solvothermal
conditions based on the aggregation-induced emission (AIE) ligand
4, 4′-(quinoxaline-2, 3-diyl)dibenzoic acid (H2DPQ). Structural analyses show that DPQ-Eu adopts
the monoclinic C2/c space group and forms a 3, 6-connected 2D porous
network with a topological symbol of {42·6}2{44·69·82}. The formation
of DPQ-Eu contributes an absolute quantum efficiency
of 21.49% compared with that of the AIE ligand H2DPQ (0.02%) mainly due to the coordination-induced emission,
providing DPQ-Eu with a great potential of being a luminescent
sensor. Fluorescent investigations show that DPQ-Eu has
a selective and sensitive response to Fe3+ and Hg2+ among various metal ions by ratiometric emission changes of the
decreased emission at 415 nm and increased emission at 676 nm, with
the detection limits of 25.99 and 39.70 nM and good reusability (5
times). The sensing behaviors probably can be ascribed to the promoted
antenna effect from the ligand to the Eu(III) center by the coordination
of Fe3+/Hg2+ to the quinoxaline moiety. For
anion sensing, DPQ-Eu can respond to Cr2O72– by emission quenching at both 415 and
676 nm with a detection limit of 9.88 nM and 5 times reusability,
probably associated with the energy competing absorption and reduced
energy transfer from the ligand to the Eu(III) center. In addition, DPQ-Eu shows ratiometric emission changes to CN– by the emission enhancement and decrease at 415 and 676 nm, respectively,
with a detection limit of 8.19 nM and five-run recycling tests, probably
corresponding to the inhibition of energy transfer from the ligand
to the Eu(III) center caused by the binding interactions between the
CN– and Eu(III) nodes.
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Xu, Siji; Xiong, Gui; Zhang, Xiang-Yu; Huang, Kun; Qin, Da-Bin; Zhao, Bin (1753). Constructing an AIE Diphenylquinoxaline-Based Luminescent
Europium-Organic Framework for Multiple Substance Sensing. ACS Publications. Collection. https://doi.org/10.1021/acs.cgd.3c00028