Condensed Phenoxazine Dimer and Its Radical Cation
Posted on 2020-08-19 - 10:29
A condensed phenoxazine dimer was
synthesized and characterized.
X-ray crystallographic analysis of the dimer shows a double-butterfly
structure, in which the nitrogen atoms are located above and below
the molecular plane. A radical cation salt of the dimer was obtained
using tris(4-bromophenyl)aminium hexafluoroantimonate as the oxidant.
The salt is air-stable in solid and solution states. The cation structure
was evaluated by X-ray crystallographic analysis, showing that the
phenoxazine units were converted to a planar structure upon oxidation.
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