Chiral Salen−Aluminum Complex as a
Catalyst for Enantioselective α-Addition
of Isocyanides to Aldehydes:
Asymmetric Synthesis of
2-(1-Hydroxyalkyl)-5-aminooxazoles
Posted on 2007-08-30 - 00:00
In the presence of a catalytic amount of (salen)Al(III)Cl complex (4e), reaction between α-isocyanoacetamides (1) and aldehydes (2) afforded
the corresponding 5-aminooxazoles (3) in good yields and enantioselectivity.
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Wang, Shi-Xin; Wang, Mei-Xiang; Wang, De-Xian; Zhu, Jieping (2016). Chiral Salen−Aluminum Complex as a
Catalyst for Enantioselective α-Addition
of Isocyanides to Aldehydes:
Asymmetric Synthesis of
2-(1-Hydroxyalkyl)-5-aminooxazoles. ACS Publications. Collection. https://doi.org/10.1021/ol7014658
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