An Unexpected SN‘ Reaction on Cobaltocenium Triflates: 
Substitution on One Ring and Elimination on the Other

Gleiter, Rolf

An Unexpected S_N‘ Reaction on Cobaltocenium Triflates: Substitution on One Ring and Elimination on the Other

Posted on 2003-05-10 - 00:00

CpCo-capped tetra-n-propylcyclopentadienone complexes were O-alkylated and O-acylated. Reactions of the O-triflated product with organolithium compounds afford a substitution of the Cp ring in 40−80% yield; as products the RCpCo-capped tetra-n-propyl-cyclopentadienone complexes were isolated.

CITE THIS COLLECTION

von der Gruen, Mareile; Schaefer, Carsten; Gleiter, Rolf (2016). An Unexpected S_N‘ Reaction on Cobaltocenium Triflates: Substitution on One Ring and Elimination on the Other. ACS Publications. Collection. https://doi.org/10.1021/om030182g

https://doi.org/10.1021/om030182g

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