An Organometallic Sandwich Lanthanide Single-Ion Magnet with an Unusual Multiple Relaxation Mechanism

Murugesu, Muralee

An Organometallic Sandwich Lanthanide Single-Ion Magnet with an Unusual Multiple Relaxation Mechanism

Posted on 2016-02-22 - 12:09

A dysprosium(III) sandwich complex, [Dy^III(COT″)₂Li(THF)(DME)], was synthesized using 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion (COT″). The complex behaves as a single-ion magnet and demonstrates unusual multiple relaxation modes. The observed relaxation pathways strongly depend on the applied static dc fields.

CITE THIS COLLECTION

Jeletic, Matthew; Lin, Po-Heng; J. Le Roy, Jennifer; Korobkov, Ilia; Gorelsky, Serge I.; Murugesu, Muralee (2016). An Organometallic Sandwich Lanthanide Single-Ion Magnet with an Unusual Multiple Relaxation Mechanism. ACS Publications. Collection. https://doi.org/10.1021/ja207891y

https://doi.org/10.1021/ja207891y

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