An Au8 Cluster Fortified by Four Ferrocenes
Posted on 2020-07-08 - 16:12
Atomically
precise metal clusters are now in the research spotlight,
owing to the precise correlation between the physicochemical properties
and their atomic-packing structures at an atomic-level. Herein we
synthesized an Au8 cluster capped by four ferrocene ligands
(DPPF), in which the ferrocene not only can direct the precise formation
of the Au8 cluster, but also can solidify the structural
pattern of the Au8 cluster. The Au8(DPPF)4 clusters as heterogeneous catalysts can achieve efficiently
catalytic performances for the CO oxidation reaction, mainly due to
the resistance to aggregation into large particles under reaction
conditions. Our results suggest that the homolytic phosphine dissociation
nature and the postdissociation reconstruction effect induced by Fe
may enhance the catalytic performances of Au8(DPPF)4.
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Li, Shuo Hao; Liu, Xu; Hu, Weigang; Chen, Mingyang; Zhu, Yan (2020). An Au8 Cluster Fortified by Four Ferrocenes. ACS Publications. Collection. https://doi.org/10.1021/acs.jpca.0c03366
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AUTHORS (5)
SL
Shuo Hao Li
XL
Xu Liu
WH
Weigang Hu
MC
Mingyang Chen
YZ
Yan Zhu