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Alkenyl Exchange of Allyl­amines via Nickel(0)-Catalyzed C–C Bond Cleavage

Version 5 2019-02-11, 15:24
Version 4 2019-02-11, 11:13
Version 3 2019-02-10, 13:13
Version 2 2019-02-09, 11:13
Version 1 2019-02-08, 20:19
Posted on 2019-02-11 - 15:24
A functional group exchange reaction between allyl­amines and alkenes via nickel-catalyzed CC bond cleavage and formation was developed. This reaction provides a novel protocol, which does not require the use of unstable imine substrates, for the synthesis of allyl­amines, which are widely used in the production of fine chemicals, pharmaceuticals, and agrochemicals.

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