Adaptable DNA-Interactive Probe Proficient at Selective
Turn-On Sensing for Al3+: Insight from the Crystal Structure,
Photophysical Studies, and Molecular Logic Gate
Posted on 2020-07-16 - 14:05
The synthesized Schiff base ligand
3-hydroxy-N′-(2-hydroxy-3-methoxybenzylidene)-2-naphthohydrazide
(H2NPV) is structurally characterized by single-crystal
X-ray
diffraction (XRD) and exhibits weak fluorescence in the excited state
owing to the effect of excited-state-induced proton transfer (ESIPT).
However, in the presence of Al3+, the ESIPT is blocked
and chelation-enhanced fluorescence (CHEF) is induced because of complexation
with the cations, resulting in turn-on emission for Al3+. The probe H2NPV selectively detects Al3+ among
the various metal ions, and the detection limit is found to be 1.70
μM. The composition and modes of complex coordination were determined
by spectroscopic, theoretical studies and molecular logic gate applications.
Finally, DNA binding studies were performed by spectroscopic and calorimetric
methods to elucidate possible bioactivity of H2NPV.
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Saha, Urmila; Das, Bhriguram; Dolai, Malay; Butcher, Ray J.; Suresh Kumar, Gopinatha (2020). Adaptable DNA-Interactive Probe Proficient at Selective
Turn-On Sensing for Al3+: Insight from the Crystal Structure,
Photophysical Studies, and Molecular Logic Gate. ACS Publications. Collection. https://doi.org/10.1021/acsomega.0c02226
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AUTHORS (5)
US
Urmila Saha
BD
Bhriguram Das
MD
Malay Dolai
RB
Ray J. Butcher
GS
Gopinatha Suresh Kumar
KEYWORDS
Crystal Structuresingle-crystal X-ray diffractiondetection limitSelective Turn-Onmetal ionsturn-on emissionPhotophysical StudiesMolecular Logic GateDNA binding studies1.70 μ MXRDprobe H 2 NPVspectroscopicexcited-state-induced proton transferESIPTH 2 NPVchelation-enhanced fluorescenceSchiff base ligand 3- hydroxyAdaptable DNA-Interactive Probe Pro...Allogic gate applications