A Hg(ClO4)2·3H2O Catalyzed Sakurai–Hosomi Allylation of Isatins and Isatin Ketoimines Using Allyltrimethylsilane

Zhou, Jian

A Hg(ClO₄)₂·3H₂O Catalyzed Sakurai–Hosomi Allylation of Isatins and Isatin Ketoimines Using Allyltrimethylsilane

Posted on 2016-02-22 - 11:23

It is reported that Hg(ClO₄)₂·3H₂O could efficiently activate the cheap but less reactive allyltrimethylsilane for the allylation of isatins or isatin ketoimines, with catalyst loading down to 0.1 mol %. This is the first example of Sakurai–Hosomi allylation of ketoimines using allyltrimethylsilane. A rare example of chiral mercury catalysis is also reported.

CITE THIS COLLECTION

Cao, Zhong-Yan; Zhang, Yan; Ji, Cong-Bin; Zhou, Jian (2016). A Hg(ClO₄)₂·3H₂O Catalyzed Sakurai–Hosomi Allylation of Isatins and Isatin Ketoimines Using Allyltrimethylsilane. ACS Publications. Collection. https://doi.org/10.1021/ol202705g

https://doi.org/10.1021/ol202705g

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