jz0c01173_si_liveslides.zip (6.35 MB)
On Librational and Rotational Motions of Aromatic Rings in Layered Sn(IV) and Zr(IV) Phosphonate Materials: A Variable-Temperature 13C, 31P Solid-State NMR Study
online resource
posted on 2020-07-02, 15:03 authored by Vladimir I. Bakhmutov, Douglas W. Elliott, Aida Contreras-Ramirez, Abraham Clearfield, Hong-Cai ZhouAccording
to the solid-state 13C, 31P NMR
study and 13C chemical shift anisotropy (CSA) measurements,
aromatic rings in the layered metal(IV) phosphonate materials behave
as low-energy rotors at rotation activation energy, Eact, of 1.4–3.0 kcal/mol. The rotational mechanism
consists of 180° flips and librations around C(1)–C(4)
axis. The amplitude of the librations, added to the flips, grows with
temperature, shifting the reorientations toward rotational diffusion
at high temperatures.
History
Usage metrics
Categories
Keywords
reorientationE actmeasurement31 P Solid-State NMR StudyMateriallibrationmechanismPhosphonateaxisdiffusion13 Crotation activation energymaterialCSALayeredSnphosphonateVariable-Temperature 13 CLibrational13 C chemical shift anisotropyAromatic RingsRotational Motions31 P NMR studykcallow-energy rotorsamplitudeZr
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC