Template-Guided Nondeterministic Assembly of Organosilica Nanodots for Multifunctional Physical Unclonable Functions

Optical physical unclonable functions (PUFs) are gaining attention as a robust security solution for identification in the expanding Internet of Things (IoT). To enhance the security and functionality of PUFs, integrating multiple optical responsessuch as fluorescence and structural colorinto a single system is essential. These diverse optical properties enable multilevel authentication, where different layers of security can be verified under varying light conditions, greatly reducing the risk of counterfeiting. However, compactly integrating these photonic components poses significant challenges due to the difficulty of aligning and combining their optical behaviors within a limited space. In this study, we address these challenges by employing a template-guided assembly of organosilica nanodots (OSiNDs), which allows for the simultaneous control of solid-state fluorescence, rainbow holography, and PUF patterns. By precisely tuning the dewetting process, the OSiNDs assemble into nanoisland structures that provide enhanced fluorescence brightness and thermal stability while maintaining distinct holographic properties. Our system produces a 4096-bit key with 3228 bits of entropy, a storage density of 1 Gbit/in², and a low false positive rate of 10^–6. Additionally, it includes multilevel anticounterfeiting features that reveal distinct color patterns under different illumination angles, further boosting security. Comprehensive environmental stability and durability tests, including humidity, thermal, and mechanical abrasion resistance, confirm the robustness of the system, ensuring its functionality under real-world conditions. This multifunctional PUF design establishes a standard for secure, compact optical systems, combining high-performance authentication with practical applications in anticounterfeiting.