posted on 2014-11-26, 00:00authored byJinlong Song, Shuai Huang, Yao Lu, Xiangwei Bu, Joseph E. Mates, Aritra Ghosh, Ranjan Ganguly, Claire
J. Carmalt, Ivan P. Parkin, Wenji Xu, Constantine M. Megaridis
Marine oil spills seriously endanger
sea ecosystems and coastal
environments, resulting in a loss of energy resources. Environmental
and economic demands emphasize the need for new methods of effectively
separating oil–water mixtures, while collecting oil content
at the same time. A new surface-tension-driven, gravity-assisted,
one-step, oil–water separation method is presented for sustained
filtration and collection of oil from a floating spill. A benchtop
prototype oil collection device uses selective-wettability (superhydrophobic
and superoleophilic) stainless steel mesh that attracts the floating
oil, simultaneously separating it from water and collecting it in
a container, requiring no preseparation pumping or pouring. The collection
efficiencies for oils with wide ranging kinematic viscosities (0.32–70.4
cSt at 40 °C) are above 94%, including motor oil and heavy mineral
oil. The prototype device showed high stability and functionality
over repeated use, and can be easily scaled for efficient cleanup
of large oil spills on seawater. In addition, a brief consolidation
of separation requirements for oil–water mixtures of various
oil densities is presented to demonstrate the versatility of the material
system developed herein.