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Download fileResonant Ptychographic Tomography Facilitates Three-Dimensional Quantitative Colocalization of Catalyst Components and Chemical Elements
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posted on 2018-09-17, 00:00 authored by Johannes Ihli, Ana Diaz, Yuying Shu, Manuel Guizar-Sicairos, Mirko Holler, Klaus Wakonig, Michal Odstrcil, Teng Li, Frank Krumeich, Elisabeth Müller, Wu-Cheng Cheng, Jeroen Anton van Bokhoven, Andreas MenzelThe ability to localize
selected chemical elements within individual
components of functional matter is of great value to our understanding
of material behavior. By means of resonant ptychographic X-ray computed
tomography, we here provide such colocalization information with nanoscopic
spatial resolution. Spatially correlated quantitative tomograms of
electron density and iron concentration allowed the localization of
native and feedstock-introduced iron impurities within the primary
components of a prominent heterogeneous catalyst. Examinations found
no direct evidence in favor of the currently suggested impurity-driven
deactivation mechanisms of fluid catalytic cracking catalysts. The
majority of iron impurities, present in the form of nanosized magnetite
particulates, are found embedded in the outermost layer of an otherwise
iron-poor, particle isolating amorphous silica–alumina envelope.
Observations query both deactivation driven by impurity pore clogging
and iron-impurity induced melting of catalyst components. The presented
approach is general, extendable to secondary impurities or materials
and spectroscopic ptychographic tomography. Future applications such
as active-site localization and speciation in heterogeneous catalysis
are envisioned.
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chemical elementselectron densityspectroscopic ptychographic tomographyimpurity poreChemical ElementsCatalyst Componentsfeedstock-introduced iron impuritiesfuture applicationsactive-site localizationnanosized magnetite particulatesoutermost layerptychographic X-rayObservations queryimpurity-driven deactivation mechanismsiron impuritiescatalyst componentscolocalization informationmaterial behaviorResonant Ptychographic Tomography Facilitates Three-Dimensional Quantitative Colocalizationiron concentration