Flexible transparent conductive films (FTCFs) with electromagnetic
interference (EMI) shielding performance are increasingly crucial
as visualization windows in optoelectronic devices due to their capabilities
to block electromagnetic radiation (EMR) generated during operation.
Metal mesh-based FTCFs have emerged as a promising representative
in which EMI shielding effectiveness (SE) can be enhanced by increasing
the line width, reducing the line spacing, or increasing mesh thickness.
However, these conventional approaches decrease optical transmittance
or increase material consumption, thus compromising the optical performance
and economic viability. Hence, a significant challenge still remains
in the realm of metal mesh-based FTCFs to enhance EMI SE while maintaining
their original optical transmittance and equivalent material usage.
Herein, we propose an innovative symmetric structural optimization
strategy to create silver mesh-based sandwich-FTCFs with arbitrary
customized sizes through high-precision extrusion printing technology
for tunable EMI shielding performance. The meticulous adjustment
of xy-axis offsets and printing starting point ensures
perfect alignment of the silver mesh on both sides of the transparent
substrate. This approach yields sandwich-FTCFs with optical transmittance
equivalent to single-layer-FTCFs under identical parameters while
simultaneously achieving up to 40% enhanced EMI SE. This improvement
stems from the synergistic effect of multiple internal reflections
and wave interference between the symmetric silver meshes. The excellent
shielding performance of sandwich-FTCFs is evidenced through effectively
blocking electromagnetic waves from common devices such as mobile
phones, Bluetooth earphones, and smartwatches. Our work represents
a significant advancement in balancing optical transmittance, EMI
SE, and material efficiency in high-performance and cost-effective
FTCFs.