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Ester Crosslinking Enhanced Hydrophilic Cellulose Nanofibrils Aerogel

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posted on 03.08.2018, 00:00 by Yulong Li, Yushang Liu, Yang Liu, Wenchuan Lai, Feng Huang, Anping Ou, Rui Qin, Xiangyang Liu, Xu Wang
The ester cross-linking of cellulose nanofibril (CNF) aerogel was carried out by a facile and highly effective gas–solid fluorinating reaction without the assistance of organic solvent. The fluorination achieved the coexistence of covalent cross-linking and more hydrophilic groups, simultaneously endowing the fluorine-treated CNFs (F-CNFs) aerogel with enduring water-durable and enhanced hydrophilic properties. Hydrogen bond interactions between cellulose nanofibers are replaced by covalent cross-linking of ester bonds, which makes the CNFs aggregate more tightly and thus facilitates the enhancement of mechanical properties of F-CNF aerogel. Meanwhile, the F-CNF aerogel exhibited ultralight weight, excellent mechanical properties (123.4 KPa at 85% strain), and water absorption (123.65 g/g), while having good shape memory performance. What’s more, there was not any exotic element introduced into F-CNFs, which can thus maximize the possibility for the final materials to maintain the excellent biological properties of the original CNFs.