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Capillary Transfer of Self-Assembled Colloidal Crystals

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posted on 2023-02-20, 12:34 authored by Carlos D. Díaz-Marín, Diane Li, Fernando J. Vázquez-Cosme, Simo Pajovic, Hyeongyun Cha, Youngsup Song, Cameron Kilpatrick, Geoffrey Vaartstra, Chad T. Wilson, Svetlana Boriskina, Evelyn N. Wang
Colloidal self-assembly has attracted significant interest in numerous applications including optics, electrochemistry, thermofluidics, and biomolecule templating. To meet the requirements of these applications, numerous fabrication methods have been developed. However, these are limited to narrow ranges of feature sizes, are incompatible with many substrates, and/or have low scalability, significantly limiting the use of colloidal self-assembly. In this work, we study the capillary transfer of colloidal crystals and demonstrate that this approach overcomes these limitations. Enabled by capillary transfer, we fabricate 2D colloidal crystals with nano-to-micro feature sizes spanning 2 orders of magnitude and on typically challenging substrates including those that are hydrophobic, rough, curved, or structured with microchannels. We developed and systemically validated a capillary peeling model, elucidating the underlying transfer physics. Due to its high versatility, good quality, and simplicity, this approach can expand the possibilities of colloidal self-assembly and enhance the performance of applications using colloidal crystals.

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