American Chemical Society
ma801802d_si_002.mpg (3.24 MB)

Bending Dynamics and Directionality Reversal in Liquid Crystal Network Photoactuators

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posted on 2008-11-25, 00:00 authored by Casper L. van Oosten, Daniel Corbett, Dylan Davies, Mark Warner, Cees W. M. Bastiaansen, Dirk J. Broer
Liquid crystalline photoactuators typically bend toward the light source, driven by the isomerization of azobenzene. In samples with a relatively large thickness and high azobenzene loading such as LC photoactuators, intense optical beams are seen to be absorbed in spatially nonexponential ways. Here we show that the dynamics of the related mechanical behavior is also strongly nonlinear, where the actuator reaches a maximum bend before unbending again to its equilibrium deformed state. The effect is amplified when combined with actuators with an internal composition gradient, leading to a reversal of the bending direction away from the light source.