A Superstretchable and Ultrastable Liquid Metal–Elastomer Wire for Soft Electronic Devices

One-dimensional (1D) elastic conductors are an important component for constructing a wide range of soft electronic devices due to their small footprint, light weight, and integration ability. Here, we report the fabrication of an elastic conductive wire by employing a liquid metal (LM) and a porous thermoplastic elastomer (TPE) as building blocks. Such an LM–TPE composite wire was prepared by electrospinning of TPE microfibers and coating of a liquid metal. An additional layer of electrospun TPE microfibers was deposited on the wire for encapsulation. The porous structure of the TPE substrate that is composed of electrospun fibers can substantially improve the stretchability and electrical stability of the composite LM–TPE wire. Compared with the wire using a nonporous TPE as a substrate, the break strain of the LM–TPE wire was increased by 67% (up to ∼2300% strain). Meanwhile, the resistance increase of the wire during 1900% strain of stretching could be controlled as low as 12 times, which is much more stable than that of other LM-based 1D elastic conductors. We demonstrate that a light-emitting diode and an audio playing setup, which use the LM–TPE wire as an electrical circuit, can work with low-intensity attenuation or waveform deformation during large-strain (1000%) stretching. For a proof-of-concept application, an elastic inductance coil was made using the LM–TPE wire as building blocks, and its potential applications in strain sensing and magnetic field detection were demonstrated.