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NO2-Mediated meso-Hydroxylation of Iron(III) Porphyrin

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journal contribution
posted on 02.03.2009, 00:00 by G. J. Abhilash, Jagannath Bhuyan, Pinky Singh, Suman Maji, Kuntal Pal, Sabyasachi Sarkar
NO2 generated from NO and air add to iron(III) porphyrin upon nitration, which isomerized spontaneously to hydrolysis, yielding a meso-hydroxylated cation that seized by the end oxidation product, a nitrate ion, through extensive hydrogen bonding.