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5-C5Me5)Ru(amidinate):  Highly Reactive Ruthenium Complexes Formally Bearing 16 Valence Electrons Showing Signs of Coordinative Unsaturation

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journal contribution
posted on 08.02.2000, 00:00 by Yoshitaka Yamaguchi, Hideo Nagashima
Novel coordinatively unsaturated ruthenium complexes, (η5-C5Me5)Ru(amidinate), were synthesized from [(η5-C5Me5)Ru(OMe)]2 and lithium amidinates, which exist as monomers in both solution and solid states and are highly reactive toward two-electron ligands.