American Chemical Society
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μ1,1-Azide-Bridged Ferromagnetic MnIII Dimer with Slow Relaxation of Magnetization

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journal contribution
posted on 2006-06-26, 00:00 authored by Chun-Hua Ge, Ai-Li Cui, Zhong-Hai Ni, Yun-Bo Jiang, Li-Fang Zhang, Joan Ribas, Hui-Zhong Kou
A new end-on azide-bridged dimeric MnIII complex has been synthesized by using the tridentate N-isonicotinamidosalicylaidimine ligand. Magnetic studies show that the complex has a high-spin ground state of S = 4 and is ac out-of-phase frequency-dependent.