μ1,1-Azide-Bridged Ferromagnetic MnIII Dimer with Slow Relaxation of
Magnetization

Ge, Chun-Hua; Cui, Ai-Li; Ni, Zhong-Hai; Jiang, Yun-Bo; Zhang, Li-Fang; Ribas, Joan; Kou, Hui-Zhong

doi:10.1021/ic060479h.s002

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μ_1,1-Azide-Bridged Ferromagnetic Mn^III Dimer with Slow Relaxation of Magnetization

journal contribution

posted on 2006-06-26, 00:00 authored by Chun-Hua Ge, Ai-Li Cui, Zhong-Hai Ni, Yun-Bo Jiang, Li-Fang Zhang, Joan Ribas, Hui-Zhong Kou

A new end-on azide-bridged dimeric Mn^III complex has been synthesized by using the tridentate N-isonicotinamidosalicylaidimine ligand. Magnetic studies show that the complex has a high-spin ground state of S = 4 and is ac out-of-phase frequency-dependent.