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o-Phenylene-Bridged Cp/Amido Titanium Complexes for Ethylene/1-Hexene Copolymerizations

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journal contribution
posted on 24.04.2006, 00:00 authored by Dae Joon Cho, Chun Ji Wu, Sujith S, Won-Sik Han, Sang Ook Kang, Bun Yeoul Lee
o-Phenylene-bridged Me3Cp/amido titanium complexes have been prepared via the Suzuki coupling reaction. Some of them show reactivity comparable to that of the CGC [Me2Si(η5-Me4Cp)(NtBu)]TiCl2 in ethylene/1-hexene copolymerization in terms of activity, molecular weight, and comonomer incorporation.