o-Phenylene-Bridged Cp/Amido Titanium Complexes for Ethylene/1-Hexene Copolymerizations

Cho, Dae Joon; Wu, Chun Ji; S, Sujith; Han, Won-Sik; Kang, Sang Ook; Lee, Bun Yeoul

doi:10.1021/om0601854.s003

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o-Phenylene-Bridged Cp/Amido Titanium Complexes for Ethylene/1-Hexene Copolymerizations

journal contribution

posted on 24.04.2006, 00:00 authored by Dae Joon Cho, Chun Ji Wu, Sujith S, Won-Sik Han, Sang Ook Kang, Bun Yeoul Lee

o-Phenylene-bridged Me₃Cp/amido titanium complexes have been prepared via the Suzuki coupling reaction. Some of them show reactivity comparable to that of the CGC [Me₂Si(η⁵-Me₄Cp)(N^tBu)]TiCl₂ in ethylene/1-hexene copolymerization in terms of activity, molecular weight, and comonomer incorporation.